Copper (I) complexes triphenylphosphine and aminophenol.

Najma Sultana; Hamida Tabassum; M. Saeed Arayne

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Copper (I) complexes triphenylphosphine and aminophenol.

Author(s)

Najma Sultana Pharmaceutical Chemistry Department, Faculty of Pharmacy, University of Karachi, Karachi, Pakistan

Hamida Tabassum Pharmaceutical Chemistry Department, Faculty of Pharmacy, University of Karachi, Karachi, Pakistan

M. Saeed Arayne Chemistry Department, University of Karachi, Karachi, Pakistan

Abstract

Some new complexes of copper (I) containing Mixed ligands having general formula [CuX(PPh3)Amph)],ICu2X2(PPh3)3(Amph) and [CunZn(PPh3)2(Amph)] [where X = Cl; Br, 1 and Z=NO3 - or SCN; n = 1,4 or 5 and PPh3 = triphenylphosphine and Am ph = aminophenol] have been synthesized from [CuX(PPh3)]4 and [CuX (Pph3)2]2 in benzene in variable ratios and characterized on the basis of infra red studies and elemental analysis. Magnetic susceptibility and conductivity measurements have also been carried out. These appear to be dimers and polymeric structures having bridging of halides, nitrate or thiocyanate groups between the two copper atoms.

Publication Details

Page(s) 167-171

DOI DOI not available

Published Journal: Pakistan Journal of Scientific and Industrial Research, Volume: 38, Issue: 5--6, Year: 1995

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