The area of research for material scientists, which has become increasingly active in recent years, has been the development of polymeric electrolytes for electro chromic devices. These materials offer some distinct advantages over conventional electrolyte systems. Conduction and mechanism of conduction in a polyelectrolyte plays an important role in determining its end use in any electro chromic device. The conduction analysis of a novel polyelectrolyte gel is reported here. The ionic conductivity was studied by AC Impedance spectroscopy using stainless steel blocking 78 e\e("i`code \n temperature awes \rom 0°C to BO°C. The ge\ was comp\exed `t c\ L\kh\Um %8% and khe condNIC`k i \s discussed, and compared \mkh conventional systems. Characterization of the polyelectrolyte gel by various techniques and thermal stability has also been done and presented here.