Silicon/Silicon Carbide/Graphite Composite Anode Material for Rechargeable Lithium-Ion Batteries by High-Temperature Vacuum Adsorption Method

Liyong Wang; Mei Wang; Huiqi Wang; Jinhua Yang; Shengsheng Ji; Lei Liu; Shengliang Hu; Quangui Guo

doi:10.52568/001466/JCSP

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Silicon/Silicon Carbide/Graphite Composite Anode Material for Rechargeable Lithium-Ion Batteries by High-Temperature Vacuum Adsorption Method

Author(s)

Liyong Wang School of Energy and Power Engineering, North University of China, Taiyuan 030001, PR China.

Mei Wang School of Energy and Power Engineering, North University of China, Taiyuan 030001, PR China.

Huiqi Wang School of Energy and Power Engineering, North University of China, Taiyuan 030001, PR China.

Jinhua Yang National Key Laboratory of Advanced Composites, AECC Beijing Institute of Aeronautical Materials, Beijing 10095, PR China.

Shengsheng Ji School of Energy and Power Engineering, North University of China, Taiyuan 030001, PR China.

Lei Liu School of Energy and Power Engineering, North University of China, Taiyuan 030001, PR China.

Shengliang Hu School of Energy and Power Engineering, North University of China, Taiyuan 030001, PR China.

Quangui Guo CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 03l0001, PR China.

Abstract

Summary:Recently, the electrode materials for next-generation lithium-ion batteries (LIBs) draw widespread attention on storing reversibly the electrical energy. For this issue, the expanded graphite and silicon particles are chosen to generate silicon/silicon carbide/graphite composite anode material using a high-temperature vacuum adsorption method. The prepared composites are measured by Xray diffraction, transmission electron microscopy, and Raman spectra, et al. The composites are cycled at a current density of 50 mA g-1, in order to observe their potential specific capacity. An initial charge capacity is 566.5 mAh g-1, and its initial Coulombic efficiency is 97.4 %. The reversible specific capacity keeps at 502 mAh g-1 after 80 cycles, displaying a capacity retention of 88.7%.

Publication Details

Page(s) 241-252

DOI 10.52568/001466/JCSP

Published Journal: Journal of Chemical Society of Pakistan, Volume: 46, Issue: 3, Year: 2024

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Keywords

Silicon, lithium-ion battery, High-temperature vacuum adsorption, Anode, Expanded graphite

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