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Comparative vapour phase FTIR studies and vibrational assignment of cyclopentadienyl-manganese-tricarbonyl and methylcyclopentadienyl-manganese-tricarbonyl.

Author(s)
Zaid Mahmood Institute of Chemistry University of the Punjab, Lahore, Pakistan
Syeda Rubina Gilani Chemistry Department, University of Engineering and Technology, Lahore, Pakistan
Abstract
The FTIR spectra in solution and vapour phase of the compounds, cyclopentadienyl manganese tricarbonyl (h-C5H5)Mn(CO)3 and methylcyclopentadienyl manganese tricarbonyl (h-C5H4CH3)Mn(CO)3 were measured in the region 4000-400 cm-1. An assignment is offered in which the normal modes are described in term of “Local symmetry”. This assignment has been discussed in term of previous assignment given for (in liquid phase and nujoll mull) other h–cyclopentadienyl and related compounds including ferrocene, dimethyl ferrocene, benzenechromium tricarbonyl and toluene chromium tricarbonyl.
Publication Details
Page(s) 582-591
DOI DOI not available
Published Journal: Journal of Chemical Society of Pakistan, Volume: 31, Issue: 4, Year: 2009

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