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The catalytic cracking mechanism of lignite pyrolysis char on tar.
Author(s):
1. Zhang Lei: Xi’an University of Science and Technology, Xi’an, China.
2. He Huibin: Xi’an University of Science and Technology, Xi’an, China.
3. Zhang Lei: China National Heavy Machinery Research Institute, Xi’an, China.
4. Sha Xiangling: Xi’an University of Science and Technology, Xi’an, China.
5. Ma Zhenhua: Xi’an University of Science and Technology, Xi’an, China.
6. Shu Hao: Xi’an University of Science and Technology, Xi’an, China.
7. Tian Ye: Xi 'an west mine environmental protection technology co., LTD, China.
Abstract:
The influence of different pyrolysis conditions for tar catalytic cracking will be analyzed according to the lignite pyrolysis char as catalyst on pyrolytic tar in this paper. The pyrolysis char what is the by-product of the cracking of coal has an abundant of pore structure and it has good catalytic activity. On this basis, making the modified catalyst when the pyrolysis char is activation and loads Fe by impregnation method. The cracking mechanism of lignite pyrolytic tar is explored by applying gas chromatograph to analyze splitting products of tar. The experimental results showed that: (1) The effect of tar cracking as the pyrolysis temperature, the heating rate, the volatilization of pyrolysis char and particle size increasing is better and better. The effect of the catalytic and cracking of lignite pyrolysis char in tar is best when the heating rate, the pyrolysis temperature, the volatiles of pyrolysis char, particle size is in specific conditions.(2) The activation of pyrolysis char can improve the catalytic effect of pyrolysis char on the tar cracking. But it reduces the effect of the tar cracking when the pyrolysis char is activation loading Fe.
Page(s): 234-239
DOI: DOI not available
Published: Journal: Journal of Chemical Society of Pakistan, Volume: 39, Issue: 2, Year: 2017
Keywords:
Coal cracking , Pyrolysis , Catalyst , Lignite Pyrolysis Char , Tar cracking , Activation
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