Abstract:
The. FTIR Spectra between 4000-400 cm" and the Raman Spectra between 1800-1200 cm"`, of the Complexes of diacetamide with metal (II) halides have been measured to distinguish the mode of coordination of ligand in these complexes. The diacetamide molecules in most of these complexes are acting as bidentate ligands, Coordinating through both of their carbonyl oxygen- atoms and are in cis - form. In Co [(DA)4 (H20)2 I Br2 , although the diacetamide molecules are in cis - form but they are either acting as monodentate ligands or possibly two ofthem are uncoordinated as in the corresponding perchlorate complexes.
Page(s):
122-124
DOI:
DOI not available
Published:
Journal: Journal of Chemical Society of Pakistan, Volume: 25, Issue: 2, Year: 2003