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Assessment of Spectral, Electrical and Physical Properties of Polyaniline-dodecylbenzenesulfonic Acid Salts
Author(s):
1. Salma Gul: National Centre of Excellence in Physical Chemistry, University of Peshawar,Peshawar,Pakistan
2. Anwar-ul-Haq Ali Shah: Institue of Chemical Sciences, University of Peshawar,Peshawar,Pakistan
3. Salma Bilal: National Centre of Excellence in Physical Chemistry, University of Peshawar,Peshawar,Pakistan
Abstract:
In the present study some results related to various properties polyaniline salt synthesized via inverse emulsion polymerization pathway [1] has been discussed. The synthesized PANI salt was found to be completely soluble in tetrahydrofuran (THF), dimethyl sulfoxide (DMSO), dimethylformamide (DMF), chloroform and in a mixture of toluene and 2-propanol. The synthesized polymer salt was also further characterized with cyclic voltammetry (CV), scanning electron microscope (SEM), X-ray diffraction (XRD), UV-vis spectroscopy and viscosity measurements. Thermogravimetric analysis (TGA) was used to analyze the thermal properties of synthesized polymer. The extent of doping of the PANI salt was determined from UV-vis spectra and TGA analysis. The activation energy for the degradation of the polymer was calculated with the help of TGA.
Page(s): 167-176
DOI: DOI not available
Published: Journal: Proceedings of Pakistan Academy of Sciences, Volume: 51, Issue: 2, Year: 2014
Keywords:
SEM , common organic solvents , UVVis spectroscopy , Polyaniline PANI , XRD , cv , Intrinsically conducting polymers , PANIDBSA salt
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