A tetranuclear copper(I)-Diisopropyldithiophosphate cluster compound Cu4[µ3-S2P(O-i-Pr)2]4 obtained from copper(II) as a starting material. | [Journal of Chemical Society of Pakistan • 2007]

Author(s):

1. H. Zhong: College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, China

2. F. Li: College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, China

3. Y. Wen: College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, China

Abstract:

A sulfur coordinated tetranuclear copper(I)-diisopropyldithiophosphate cluster compound Cu4[µ,-S2P(O-i-Pr)2]4 was synthesized by the reaction of Na[S2P(O-i-Pr)2] with CuCI2 and its structure was characterized by X-ray crystallography. The cluster compound crystallizes in the tetragonal system, space group 14(l)/a. The four symmetry-equivalent Cu(I) atoms are arranged in a tetrahedral geometry and two S-atoms of each dithiophosphate ligand are coordinated monodentate and bidentate respectively to triangular Cu3 units.

Page(s): 41-43

DOI: DOI not available

Published: Journal: Journal of Chemical Society of Pakistan, Volume: 29, Issue: 1, Year: 2007

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