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A new Family of Energetic Complexes Constructed from Alkali Metals (K, Rb and Cs) and 7-amino-4,6-dinitrobenzofuroxan: Crystal Structures, Thermal Decomposition Behaviors, Sensitivity and Catalytic Properties.
Author(s):
1. Jian Cheng: Department of safety science and engineering, Zhejiang University of Technology,Hangzhou, 310014,China
2. Zuliang Liu: School of Mechanical Engineering, Nanjing University of Science and Technology,Nanjing, 210094,China
3. Zhenming Li: Department of safety science and engineering, Zhejiang University of Technology,Hangzhou, 310014,China
4. Yan Dong: Shijiazhuang No.4Pharmaceutical Co.,Ltd.,Shijiazhuang,050021,China.
5. Yu Zheng: School of Mechanical Engineering, Nanjing University of Science and Technology,Nanjing, 210094,China
6. Rui Wang: Department of safety science and engineering, Zhejiang University of Technology,Hangzhou, 310014,China
7. Li Sun: Department of safety science and engineering, Zhejiang University of Technology,Hangzhou, 310014,China
Abstract:
Summary: This work reported a new family energetic complexes constructed from alkali metals (K, Rb and Cs) and 7-amino-4,6-dinitrobenzofuroxan (ADNBF). The crystal structures, thermal decomposition behaviors, sensitivity and catalytic properties of the novel materials were characterized by using X-ray diffraction, TG-DSC measurements and mechanical sensitivity tests. These crystals belonged to a triclinic and monoclinic system with space group P-1 and P21/n. ADNBF and complexes 1-3 exhibited one exothermic process with an exothermic peak temperature of about 265 oC, and the trend of thermal stability for ADNBF and complexes 1-3 was found to be in the order of 1<2<3
Page(s): 311-318
DOI: DOI not available
Published: Journal: Journal of Chemical Society of Pakistan, Volume: 40, Issue: 2, Year: 2018
Keywords:
Energetic complex , 6dinitrobenzofuroxan
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