Using Heterocycle to Improve the Selectivity of Rhodamine-6G Dye: Synthesis of Pyrrole-modified Rhodamine-6G and its Recognition to Zn2+. | [Journal of Chemical Society of Pakistan • 2019]

Author(s):

1. Rui Qiao: School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China ; Anhui Province Key Laboratory for Degradation and Monitoring of Pollution of the Environment, China

2. Hai Yun Fan: School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China

3. CuiBing Bai: School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China ; Anhui Province Key Laboratory for Degradation and Monitoring of Pollution of the Environment, China

4. Ling Dai: School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China

5. Lin Zhang: School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China ; Anhui Province Key Laboratory for Degradation and Monitoring of Pollution of the Environment, China

6. Jie Zhang: School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China

7. Shui Sheng Chen: Anhui Province Key Laboratory for Degradation and Monitoring of Pollution of the Environment, China School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China

8. Hui Miao: School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, Anhui Province, China ; Anhui Province Key Laboratory for Degradation and Monitoring of Pollution of the Environment, China

Abstract:

Summary: The fluorescent sensor XQN for Zn2+ based on rhodamine-6G have been designed and synthesized. XQN showed fluorescent specific selectivity and high sensitivity for Zn2+ against other metal ions such as Fe3+, Cr3+, Hg2+, Ag+, Ca2+, Cu2+, Pb2+, Cd2+, Ni2+, Co2+ and Mg2+ in CH3CNPBS(phosphate buffer saline) (10 mM, v/v=7:3, pH = 7.4) solution. The distinct color change and the rapid emergence of fluorescence emission provided naked-eyes detection for Zn2+. The test strip results showed that these sensors could act as a convenient and efficient Zn2+ test kit. The recognition mechanism of the sensor toward Zn2+ was evaluated by IR and the Job's plots. The detection limits of XQN towards Zn2+ was calculated as 2.39 µM. In addition, XQN-Zn2+ fluorescence lifetime and fluorescence quantum yield were also measured.

Page(s): 300-307

DOI: DOI not available

Published: Journal: Journal of Chemical Society of Pakistan, Volume: 41, Issue: 2, Year: 2019

Keywords:

Keywords are not available for this article.

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