The Crystal Structure of Lanthanoid Hexanitrite Complexes, A2A'Ln(N02)6. | [Journal of Chemical Society of Pakistan • 1980]

Author(s):

1. JOHN C. BARNES: Chemistry Department University of Dundee Dundee DD] 4HN Scotland,

2. KHALED AL-RASOUL: Chemistry Department University of Dundee Dundee DD] 4HN Scotland,

3. PATRICK HARKINS: Chemistry Department University of Dundee Dundee DD] 4HN Scotland,

Abstract:

Summary: A single crystal structure of CS2NaLa(NO )6 and powder deter mina tion of Cs NaNd-(N02)6 and Rb~NaY(N02)6 show that these compounds 6ave the lanthanoid ion oxygen coorainated and the soidum ton nitrogen coordinated in an inverse A2A'M(N02)6 structure. La-O = 2.82 A, Na = 2.50 A Cs-O = 3.33 A, Rb-O = 3.23 A. There is no evidence for the existence of strong complex ions in this structure.

Page(s): 9-14

DOI: DOI not available

Published: Journal: Journal of Chemical Society of Pakistan, Volume: 2, Issue: 1, Year: 1980

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