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The dehydration sequence of nickel-exchanged A zeoiites
Author(s):
1. S. Akbar: Chemistry Department, University of Baluchistan, Quetta, Pakistan
Abstract:
Five nickel (II) A - Zeolites (16.6-76.6% exchanged) were investigated using volumetric, gravimetric, spectroscopic and magnetic susceptibility techniques. Upto 65% exchanged the following vacuum dehdration sequence was determined: Ni2+-(H2O)6 (Octahedral) 340K Ni2+ +-(H2O)3 (Ox)3 (Trigonal) bipyramid) 620K Ni2+(Ox)3 (Trigonal) (Where +(Ox) represents the oxygen atom of the lattice of the zeolite). All the zeolites except 77% exchanged, showed the retension of the aluminositcate framework structures both after preparation and upto 620K evacuation.
Page(s): 71-75
DOI: DOI not available
Published: Journal: Journal of Chemical Society of Pakistan, Volume: 4, Issue: 2, Year: 1982
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