Abstract:
A nido-closo-nido interconversion reaction of 7-Me3N-nido- 7-C1310H12 is discussed. Nido[8110-7-CBioH12]. anion is obtained from the reaction of 7-Me3H-pido- 7-CB1oH12 with sodium hydride. At ambient temperature the initial product is the deprotonated species, nido- [7-Me3N-7-CH1oH I]-, but after reflux and hydrolysis the isolated product is the nido-[8-H0-7-CH1oH12]. anion with the closo[2- CBioHli]- as an intermediate. The results unambiguously show [OH] substitution at B(8) position.
Page(s):
38-40
DOI:
DOI not available
Published:
Journal: Journal of Chemical Society of Pakistan, Volume: 13, Issue: 1, Year: 1991