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A novel synthesis of nido-[8-H0-7-CB101-112]- Anion.
Author(s):
1. Shah Alam Khan: Pakistan Council of Scientific and Industrial Research (PCSIR) Laboratories, Peshawar, Pakistan
Abstract:
A nido-closo-nido interconversion reaction of 7-Me3N-nido- 7-C1310H12 is discussed. Nido[8110-7-CBioH12]. anion is obtained from the reaction of 7-Me3H-pido- 7-CB1oH12 with sodium hydride. At ambient temperature the initial product is the deprotonated species, nido- [7-Me3N-7-CH1oH I]-, but after reflux and hydrolysis the isolated product is the nido-[8-H0-7-CH1oH12]. anion with the closo[2- CBioHli]- as an intermediate. The results unambiguously show [OH] substitution at B(8) position.
Page(s): 38-40
DOI: DOI not available
Published: Journal: Journal of Chemical Society of Pakistan, Volume: 13, Issue: 1, Year: 1991
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