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Synthesis, crystal structure and fungicidal activity 3-(((4-cyclopropyl-5-methyl-4H-1,2,4-triazol-3 yl)thio) methyl) benzonitrile H2O (1:1) solvent.
Author(s):
1. Jian-Zhong Jin: College of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou, Zhejiang, China
2. Na-Bo Sun: College of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou, Zhejiang, China
Abstract:
The title compound (C14H14N4S·H2O) were synthesized and recrystallized from ethanol. The compound was characterized by 1H NMR, elemental analyses and X-ray diffraction. The compound crystallized in the monoclinic space group P2(1)/c with a = 11.289(2), b = 15.675(3), c = 8.4835(17) Å, α = 90, β = 104.65(3), γ =90°, V = 1452.4(5) Å3, Z = 4 and R = 0.0333 for 2545 observed reflections with I > 2σ(I). X-ray analysis reveals that not only intermolecular O–H···N interactions. The biological activities results showed that the title compound exhibited significant fungicidal activity towards six test fungi.
Page(s): 956-960
DOI: DOI not available
Published: Journal: Journal of Chemical Society of Pakistan, Volume: 35, Issue: 3, Year: 2013
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