Abstract:
Summary: All oxygen atoms of the anions and all nitrogen atoms of the cations participate in extended hydrogen bond networks in both (CH N3)2HP03,(CH3)2CO [Pna21, a = 13.888(7), b = 9.658(4), c = 9.561(4) A, Z = 4) and (CH6N3)3~C6H5P03)' 2H20 [Cc, a = 18.51(1), b = 7.586(3), c = 12.48(1) A, (3 = 121.6(1)0, Z = 4). The lattice solvent molecules are also involved in hydrogen bonding; their presence as spacers is required by the non-planarity of the anions. The N..O distances range from 2.78 to 3.10 A. The structures were solved from photographic data, with respective residuals 0.055 for 723 reflections and 0.048 for 1268 reflections.t
Page(s):
145-150
DOI:
DOI not available
Published:
Journal: Journal of Chemical Society of Pakistan, Volume: 2, Issue: 4, Year: 1980