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Bromination of benz[f]indene: synthesis of new benz[f]indane derivatives.
Author(s):
1. Ahmet Tutar: Department of Chemistry, Faculty of Art and Science, Sakarya University, TR-54187 Adapazari, Turkey
2. Ramazan Erenler: Department of Chemistry, Faculty of Art and Science, Gaziosmanpasa University, TR-60240 Tokat, Turkey
Abstract:
The bromination reactions of benz[f]indene 1 were investigated with molecular bromine and photobromination. Dibromo- and tribromobenz[f]indane were synthesised by bromination of benz[f]indene 1. Subsequent reactions of dibromobenz[f]indane 2 were accomplished with various silver salts (silver acetate, perchlorate, sulphate and nitrate). Treatment of trans-1-acetate-2-bromobenz[f]indane 6 with sodium methoxide resulted in the formation of corresponding 1,2-oxidebenz[f]indane 10.
Page(s): 1527-1531
DOI: DOI not available
Published: Journal: Journal of Chemical Society of Pakistan, Volume: 34, Issue: 6, Year: 2012
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