The crystal_structure of lanthanoid hexanitrite complexes, A2, ALn (NO2) 6. | [Journal of Chemical Society of Pakistan • 1980]

Author(s):

1. John C. Barnes: Chemistry Department, University of Dundee, Dundee, Scotland

2. Khaled Al-Rasoul: Chemistry Department, University of Dundee, Dundee, Scotland

3. Patrick Harkins: Chemistry Department, University of Dundee, Dundee, Scotland

Abstract:

A single crystal structure of Cs2NaLa(NO)6 and powder determination of Cs2NaNd - (NO2)6 and Rb2 Nay2 (NO2,)6 show that these compounds have the lanthanoid ion oxygen coordinated and the sodium ion nitrogen coordinated in an inverse A2 A M (NO2)6 structure La-0=2.82 A, Na=2.50 A Cs-0=3.33 A,Rb-0=3.23 A. There is no evidence for the existence of strong complex ions in this structure.

Page(s): 9-14

DOI: DOI not available

Published: Journal: Journal of Chemical Society of Pakistan, Volume: 2, Issue: 1, Year: 1980

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