The Re-extraction of Oil from Oil Palm Empty Fruit Bunch Residues and Oil Palm Mesocarp Fibers and Measures in Reducing Greenhouse Gas Emission. | [Asian Journal of Agriculture and Biology • 2017]

Author(s):

1. Hotman Manurung: Study Program of Natural Resource and Environmental Management, Graduate School University of Sumatera Utara, Jalan. Prof. Maas, Medan, Indonesia: Department of Agricultural Products Technology Faculty of Agriculture, University of HKBP Nommensen, Jalan Sutomo No.4A Medan 20234

2. Jansen Silalahi: Department of Pharmaceutical Chemistry, Faculty of Pharmacy, University of Sumatera Utara, Jalan. Tri Dharma No. 5 Medan 20155,

3. Donald Siahaan: Indonesian Oil Palm Research Institute, Jalan. Brigjen Katamso 51 Medan 20158,

4. Elisa Julianti: Department of Food Science, Faculty of Agriculture, University of Sumatera Utara, Jalan. Prof. Sofyan No. 3 Medan 20155

Abstract:

Oil palm Mill (POM) produces oil palm empty fruit bunches (EFBs) and oil palm mesocarp fibers (OPMF) which still contain oil and carotenoids. POM utilizes EFBS and OPMF as a fuel to heat up the boiler and to generate electrical energy leading to the dissolve of oil and carotenoids in vain and causes greenhouse gas (GHG). The research is aimed at isolating and investigating the quantity and quality of oil of EFBS and OPMF, OPMF oil characteristics comprising of fatty acid composition and antioxidant activity and to determine the effect of GHG emission reduction after OPMF oil is macerated. The residual sample used is collected from 4 POMs. Oil isolation was done by maceration. EFBS and OPMF were compared with a hexane ratio of 1:20 (w/w), while the duration for maceration lasted for 48 hours in a room with temperature. Oil quantity parameters include residual oil content with soxhlet method and macerated oil yield. Oil quality parameters include: carotenoid levels, deterioration of bleachability index (DOBI) and free fatty acids (FFA). OPMF oil characteristics included oil fatty acid composition which was determined by GC method and antioxidant activity with 1,1-Diphenyl-2-picrylhydrazyl (DPPH) and GHG reduction by emission factor method. The quantity and quality of oil isolated from OPMF residues is higher than oil isolated from EFBS due to: oil content was higher by 3.91% (2.86% in EFBS), oil yield was 3.47% (2.26% in EFBS) carotenoid levels were higher at 2305 ppm (915.25 ppm in EFBS), DOBI is higher by 3.49 (1.14 in EFBS), and FFA is lower by 9.68% (21.58% in EFBS). The fatty acid in OPMF oil has generally the same composition as the CPO fatty acid which is dominated by palmitic acid by C16:0 and oleic acid by C18:1, respectively at an average of 30.31% at CPO of 44.0%) and 33.22% at CPO of 39.2%). OPMF Oil antioxidant activity half maximal inhibitory concentration (IC50) was at 8.49 ppm. The effect of GHG emission reduction after OPMF oil macerated could reach 88.77% of the total amount of GHG emissions resulted from OPMF burning before maceration.

Page(s): 337-345

DOI: DOI not available

Published: Journal: Asian Journal of Agriculture and Biology, Volume: 5, Issue: 4, Year: 2017

Keywords:

Keywords are not available for this article.

References:

[1] AOCS, 1987.Official Methods and Recommended Practices of the AOCS, -

[2] BessouCA,ChaseLD,HensonIE,Abdul-MananAF,CanalsLE,AgusF,SharmaMG,ChinMH, 2014.Pilot application of PalmGHG, the RSPO greenhouse gas calculator for oilpalm products,J. Cleaner Prod 15 136 -145

[3] BernasconiG,GersterH,HauserH,StaubleH,SchneiterE, 1995.Teknologi kimia. Bagian 2, 177 -186

[4] ChooYM,YapSC,OngASH,OoiCK,GohSH, 1989.American Oil Chemist's Society (AOCS),Proceedings of the AOCS World Conference of Edible Fats 111 436 -440

[5] Firman M and dan PutraE,capai-,-, 2017.-sawit-ditargetkan-,[20 Maret -

[6] GAPKI,-, 2017.Refleksi Industri kelapa Sawit 2016 dan Prospek tahun 2017,/[21 Maret -

[7] GordonMH,J.F. Hudson, 1990.The Mechanism of Antioxidant Action in Vitro,Food Antioxidant, Elsivier Applied Science -

[8] GuravS,DeskharN,GulkariV,DurangkarN,PatilA, 2007.Free radical scavenging activity of polygala chinensis Linn, 2 245 -253

[9] HassanS,KeeLS,Al-KayiemHH, 2013.Experimental study of palm oil mill effluent and oil palm frond waste mixture as an alternative biomass fuel,J. Eng. Sci. Technol 8 703 -712

[10] IPCC,Energy, 2006.Guidelines for National Greenhouse Gas Inventories,Chapter 2 47 -2

[11] JaswirI,NoviendriD,Fitri Hasrini R and Fitri Octavianti, 2011.Carotenoids: source, medicinal properties and their application in food and nutraceutical industry,J. Medicinal Plants Res 5 7119 -7131

[12] KupanS,KulkarniAD,HamidH,dan YusoffMM, 2005.Extraction of palm carotenes and effect of oxidative degradation on β-carotene,Int. J. Eng. Res. Technol 4 662 -667

[13] KurniawatiPT,SoetjiptoH,dan LimantaraL, 2007.Aktivitas antioxidant dan antibakteri pigmen bixin selaput biji kesumba (Bixa orellana),Indo. J. Chem 7 88 -92

[14] Levin G and Mokaday,S, 1994.Antioxidant activity of 9-cis compared to all-transβ-carotene in vitro,Free Radical Biol. Med 17 77 -82

[15] MahmudNRA,HastonoAD,dan PrasetyoA, 2010.Penentuan nilai kalor berbagai komposisi campuran bahan bakar minyak nabati,Alchemy 1 53 -103

[16] MajidAR,MohammadAW,YuenMC, 2012.Properties of residual palm pressed fibre oil,J. Oil Palm Res 24 1310 -1317

[17] ManasikaA,dan WidjanarkoSB, 2015.Ekstraksi pigmen karotenoid labu kabocha menggunakan metode ultrasonic (kajian rasio bahan:pelarut dan lama ekstraksi),J. Pangan dan Industri 3 928 -938

[18] MardawatiE,AchyarCS, 2008.Kajian aktivitas antioksidan ekstrak kulit Manggis (Garcinia mangostana L.) dalam rangka pemanfaatan limbah kulit manggis di Kecamatan Puspahiang Kabupaten Tasikmalaya,and dan Marta H -

[19] Masni,KajianPemanfaatan Limbah Serat Sawit Sebagai Sumber Karotenoid. Disertasi Sekolah Pascasarjana,IPB, 2004., -

[20] MediaPerkebunan, 2016.Nilai Tambah Biomassa Sawit Harus Ditingkatkan, 30 -31

[21] NaibahoPM, 1998.,Pusat penelitian Kelapa Sawit, Medan -

[22] NasutionMA,HerawanT,RivanM,, 2014.Analysis of palm biomass as electricity from palm oil mills in North Sumatera,Energy Procedia 47 166 -172

[23] NurcahyonoID,dan ZubaidahE, 2015.Pengaruh konsentrasi carboxymethyl cellulose sebagai edible coating dan suhu pengeringan terhadap sifat fisik dan kimia wortel kering instan,J. Pangan dan Agroindustri 3 1192 -1202

[24] NeohBK,ThangYM,ZainMZM,JunaidiA, 2011.Palm pressed fibre oil: a new opputonity for premium hardstock,Int. Food Res 18 769 -773

[25] OhimainEI,IzahSC,ObiezeFAU, 2013.Material balance of smallholder oil palm processing in the Niger Delta Nigeria,Advance J. Food Sci. Technol 5 289 -294

[26] OlisaYP,KotingoKW, 2014.Utilization of palm oil empty fruit bunch (PEFB) as solid fuel for steam boiler,European J. Engin Technol 2 1 -7

[27] PASPI, 2016.Akankah makin berkilau?,Monitor 1 239 -245

[28] PORIM, 1995.PORIM test methods,Palm Oil Research Institute of Malaysia. Ministry of Primary Industries -

[29] PrakashA, 2001.Antioxidant activity,Medallion Laboratories: Analytical Progress 19 1 -4

[30] PutriFD,ZuchraH,dan DrastinawatiD, 2015.Pembuatan biodiesel dari minyak sawit off grade menggunakan katalisCaO melalui proses dua tahap,J. Rekayasa Kimia dan Lingkungan 10 99 -105

[31] RubalyaVS,NeelameganP, 2012.Antioxidant potential in vegetable oil,Res. J. Chem. Environ 16 87 -94

[32] RymbaiH,SharmaRR,SrivastavM,, 2011.Bio colorants and its implication in health and food industry- A review,Int. J. Pharma Tech. Res 3 2228 -2244

[33] SubramaniamV,MenonNR,SinH,MayCY, 2013.The development of residual oil recovery system increase the revenue of palm oil mill,J. Oil Palm Res 25 116 -122

[34] SundramK,SambathamurthiR,TanYA, 2003.Palm Fruit Chemistry and Nutrition,Asia Pacific J. Clin. Nutri 12 355 -362

[35] SchroederMT,BeckerEM,SkibstedLH, 2006.Molekuler mechanism of antioxidant synergism of tocotrioenols and carotenoids in palm oil,J. Agri. Food Chem 54 3445 -3450

[36] WulandariN, 2007.Produksi konsentrat karotenoid dari fraksi cair minyak sawit menggunakan metode kromatografi kolom adsorpsi,J. Ilmu Pertanian Indonesia 12 28 -34

[37] YunosMD,BaharuddinAS,KH , Hafid,HS , Busu,Z , Mokhtar,MN , Sulaiman,A and Md,Som A, 2015.The physicochemical characteristics of residual oil and fibers from oil palm empty fruit bunches,Bio Resource 10 14 -19

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