The Synthesis of Porous Aminated Starch for the Adsorption of Phenol | [Journal of Chemical Society of Pakistan • 2024]

Author(s):

1. Lu Ning: China Tobacco Hubei Industrial Co. LTD, Wuhan, China, 430040.

2. Xiangda Liu: School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, China, 430070.

3. Yitong Ji: School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, China, 430070.

4. Xiaojie Ren: School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, China, 430070.

5. Rui Hu: School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, China, 430070.

6. Yi Jin: School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, China, 430070.

7. Guangyuan Yang: China Tobacco Hubei Industrial Co. LTD, Wuhan, China, 430040.

8. Xueyuan Yang: School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, China, 430070.

Abstract:

* Xueyuan Yang and Yitong Ji contribute the same to the article and are the corresponding authors Summary: Starch, an affordable and biodegradable polymer, is commonly used for adsorbing chemical hazards like phenol. To enhance phenol adsorption, a porous aminated starch was developed through enzymatic and chemical modification. By optimizing enzymatic reaction time and temperature, the porous starch was successfully fabricated without granule collapse, resulting in a surface area increase from 0.33 m2/g to 0.81 m2/g. Amino groups were then added to the porous starch via amination, boosting phenol adsorption capability from 0.0165 g/g in native starch to 0.0198 g/g in porous aminated starch, marking over 20% improvement. Additionally, the porous aminated starch exhibited a considerably faster adsorption rate than native starch. The porous structure provided more active sites for phenol adsorption, while the additional amino group enhanced interaction with phenol through hydrogen bonding, leading to higher phenol adsorption capability and faster rate.

Page(s): 491-498

DOI: 10.52568/001554/JCSP

Published: Journal: Journal of Chemical Society of Pakistan, Volume: 46, Issue: 5, Year: 2024

Keywords:

starch , Aminated , Phenol Adsorption , Porous

References:

[1] Conde-Petit B.,Escher F.,Nuessli J. .2006 .Structural features of starch-flavor complexation in food model systems. Trends Food Sci. Technol, 17(227) : .

[2] Tester R.F.,Karkalas J.,Qi X. .2004 .Starchcomposition, fine structure and architecture. J. Cereal Sci., 39(151) : .

[3] Chen L.,Qiu X.,Deng M.,Hong Z.,Luo R.,Chen X.,Jing X. .2005 .The starch grafted poly (l-lactide) and the physical properties of its blending composites. Polymer, 46(5723) : .

[4] Qi Q.,Wu Y.,Tian M.,Liang G.,Zhang L. .2006 .Modification of starch for high performance elastomer. Polymer, 47(3896) : .

[5] Guo L.,Zhu Y.,Du X. .2012 .The effect of modified starches on the adsorption of cigarette mainstream smoke composition. Starch‐Stärke, 64(552) : .

[6] Chen N.,Gao H. X.,He Q.,Yu Z. L.,Zeng W. C. .2020 .Interaction and action mechanism of starch with different phenolic compounds. Int. J. Food Sci. Nutr, 71(726) : .

[7] Chen N.,Gao H. X.,He Q.,Yu Z. L.,Zeng W. C. .2022 .Influence of structure complexity of phenolic compounds on their binding with maize starch. Food Struct, 33(100286) : .

[8] Zhu F. .2015 .Interactions between starch and phenolic compound. Trends Food Sci. Technol, 43(129) : .

[9] Chen J.,Wang Y.,Liu J.,Xu X. .2020 .Preparation, characterization, physicochemical property and potential application of porous starch: A review. Int. J. Biol. Macromole, 148(1169) : .

[10] Monroy Y.,Rivero S.,García M. A. .2018 .Microstructural and techno-functional properties of cassava starch modified by ultrasound. Ultrason, 42(795) : .

[11] Liu H.,Yu L.,Dean K.,Simon G.,Petinakis E.,Chen L. .2009 .Starch gelatinization under pressure studied by high pressure DSC. , 75(395) : .

[12] Hu X.,Wang Y.,Liu C.,Jin Z.,Tian Y. .2018 .‐ButanolHydrochloric Acid Hydrolysis of High‐Amylose Maize Starch. , 70(1700359) : .

[13] Singh S.,Saxena D. C. .2019 .Influence of alkali treatment on physicochemical, pasting, morphological and structural properties of mango kernel starches derived from Indian cultivars. Int. J. Biol. Macromole, 125(203) : .

[14] Benavent-Gil Y.,Rosell C. M. .2017 .Comparison of porous starches obtained from different enzyme types and levels. , 157(533) : .

[15] Guo J.,Li Y.,Gui Y.,Zhu B.,Yu C.,Tan Y.,Fang B.,Cui B. .2020 .Porous starches modified with double enzymes: Structure and adsorption properties. Int. J. Biol. Macromole, 164(1758) : .

[16] Latip D. N. Hj,Samsudin H.,Utra U.,Alias A. K. .2021 .Modification methods toward the production of porous starch: A review. Crit. Rev. Food Sci. Nutr, 61(2841) : .

[17] C. Qiu Y.,Qin S.,Zhang L.,Xiong Q.,Sun Q. .2016 .A comparative study of size-controlled worm-like amylopectin nanoparticles and spherical amylose nanoparticles: Their characteristics and the adsorption properties of polyphenols. Food Chem, 213(579) : .

[18] Luo Z.,Chen X.,Fu X.,Peng F.,Luo F. .2013 .Preparation and properties of enzyme-modified cassava starch-zinc complexes. J. Agric. Food Chem, 61(4631) : .

[19] Xie X.,Zhao X.,Luo X.,Zhang Y.,Qin Z.,Ji H. .2023 .Characterization of Modified Mechanically Activated Cassava Starch Magnetic Porous Microspheres and Its Adsorption for Cd (II) Ions. , 13(513) : .

[20] Haq F.,Yu H.,Wang Y.,Wang L.,Haroon M.,Khan A.,Mehmood S.,Lin T.,Mole T. .2020 .Synthesis of carboxymethyl starch grafted poly (methacrylic acids) (CMS-g-PMAAs) and their application as an adsorbent for the removal of ammonia and phenol. , 1207(127752) : .

[21] Haq F.,Yu H.,Wang Y.,Wang L.,Mehmood S.,Haroon M.,Fahad S.,Uddin M. A.,Shen D. .2021 .Synthesis of succinylated starches and their application as adsorbents for the removal of phenol. J. Polym. Environ., 29(2676) : .

[22] M. Haroon L.,Wang H.,Yu N. M.,Abbasi M.,Saleem R. S.,Ullah Q.,Chen Q. .2016 .Chemical modification of starch and its application as an adsorbent material. RSC Adv., 6, (78264) : .

[23] M. A. Otache R. U.,Duru O.,Achugasim O. J.,Abayeh O. J. .2021 .Advances in the modification of starch via esterification for enhanced properties. J. Polym. Environ., 29(1365) : .

[24] Bagheri A.,Hoseinzadeh H.,Hayati B.,Mahmoodi N.M.,Mehraeen E. .2021 .Post-synthetic functionalization of the metal-organic framework: Clean synthesis, pollutant removal, and antibacterial activity. Journal of Environmental Chemical Engineering, 9(104590) : .

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